First of all, the full meaning of PVD is Physical Vapor Deposition, while the full meaning of CVD is Chemical Vapor Deposition. These are two different techniques that are commonly used in creating thin films -forming a substrate from a very thin layer material. These depositions are different majorly in the processes that they employed. Just as their full names imply, CVD makes use of chemical processes to deposit the layer, while PVD makes use of physical forces for the layer's deposition.
When it comes to PVD, you gasified a pure source material via evaporation, applying the laser ablation, high power electricity, and some other techniques. Afterward, the desired layer is created after the gasified material has condensed on the substrate material. When it comes to CVD, the source material is mixed with a precursor that is volatile, which acts as a carrier, and it is not pure.