In a cryogenic gas or liquid, such as neon or helium, an electron bubble is the empty space around a free electron. Electron bubbles are very small, measuring approximately 2nm in diameter when at atmospheric pressure. There is also theoretical probability that a 2s electron bubble exists. This type of bubble has a spherical wave function but the shape when stable is nonspherical. The 2S electron bubble is supposed to reflect a unique morphological instability when placed under intense, ambient pressure.
The electron bubble theory was developed when it was realized that below a certain temperature, the mobility of electrons drops drastically. Otherwise, in noble gasses at room temperature, typically electrons move about freely. That is why at such low temperatures, electrons actually do not move about freely and they form small ‘bubbles’ around themselves instead. The size of an electron bubble varies according to three main factors. Those factors are: the amount of confinement, surface tension, and pressure-volume.