Yes, green is the rarest colour of human eyes, and it is most dramatic in North African people, probably because of its contrast with coffee coloured skin. Brown-eyed people are not that common, only 5.9% of the world population, but only around 2% has green colored eyes.
Green eye color occurs when there's a mild amount of pigmentation in the eye with a golden tint. It's thought it is caused by the migration of peoples from North to south.