Before quantum mechanics were discovered, physicists knew of no force capable of supporting any star against such gravitational pressure. Quantum mechanics, though, suggested a new way for a star to hold itself up against the force of gravity. The rules of quantum mechanics note that no two electrons can be in the exact same state. Inside an dense star, this means some electrons are forced out of low energy states into higher ones, generating a pressure called electron degeneracy pressure that resists the gravitational force.
This discovery was made by Ralph Fowler, who would later become the graduate supervisor of physicist Subrahmanyan Chandrasekhar. Chandrasekhar, however, realized what Fowler had overlooked. The high-energy electrons inside the white dwarf would have to be traveling at velocities near the speed of light, invoking a set of bizarre effects. When Chandrasekhar took these effects into account, something spectacular happened.
He found a firm upper limit for the mass of any body which could be supported by electron degeneracy pressure. Once this limit, the Chandraskehar limit, was exceeded, the object could no longer resist the force of gravity, starting to collapse.