How do metals like iron exhibit variable valency? - ProProfs Discuss
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How do metals like iron exhibit variable valency?

How do metals like iron exhibit variable valency?

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Asked by F.William, Last updated: Nov 10, 2024

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Bergeront Tiffney

Bergeront Tiffney

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Bergeront Tiffney
Bergeront Tiffney, Computer Engineer, M. Tech, Southeast Montgomery

Answered Jan 28, 2021

Iron is an example of transition metals. This set of elements are known for having variable valency. The reason why transition elements like iron have variable valency is that the electrons in their d-orbitals can also be used for bonding.

That is possible because the difference in the energy level of d-orbitals and s-orbitals is negligible. As a result, the electrons in the incomplete d-shell can be used for bonding. In the case of iron, it has the atomic configuration of 1s2 2s2 2p6 3s2 3p6 3d6 4s2. However, it will first use the two electrons in the 4s orbital for bonding, meaning it has lost two of its electrons.

At this point, the atomic configuration of 1s2 2s2 2p6 3s2 3p6 3d6 shows that it has donated two electrons. Also, iron can decide to donate three electrons, meaning one of the electrons in the 3d orbital will be part of the three electrons to be donated. That is why Iron has oxidation states of +2 and +3.

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E. Reyes

E. Reyes

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E. Reyes
E. Reyes, Builder, graduate, Birmingham

Answered Jan 21, 2021

Ion and other metals like it have variable valency because they are transition metals. All metals that are transition metals will have variable valency. It occurs when the d-orbitals lose valence electrons, and then they form bonds with different types of elements. Another reason why these metals have variable valency is that they have different electronic numbers.

For example, ions can have oxidation numbers that are +3 or +2, which will depend on the energy that is the orbital of the ion. To represent variable valency, the element would have a Roman numeral that is used as a subscript, and it would be next to the element symbol. An example is PVCl5.

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R. Barnes

R. Barnes

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R. Barnes
R. Barnes, Professional Gamer, Graduation, Oakland

Answered Jan 21, 2021

The best way to understand what variable valency is is to gain knowledge about the valency of an atom. Orbiting electrons are outside of the nucleus of an atom. The electrons that orbits are looking to donate or accept electrons. The electrons that are either given away or obtained are for the purpose of becoming more stable. There are many transitional metals that have variable valency, including iron, tin, nickel, and copper.

With iron, it loses three electrons. These electrons then will form a bond with oxygen that is ionic. This, in turn, creates the compound, which goes by the name of ferric oxide.

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S. Barnes

S. Barnes

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S. Barnes
S. Barnes, Chauffeur, Graduate, Seattle

Answered Jan 21, 2021

Many metals, such as iron, have a variable valency. If you do not know, a valency is the amount of hydrogen atoms that can be combined or displaced to create a compound. How electrons are combined and shared can depend on how the reaction occurs.

An example of this is with iron that combines with oxygen. When these two combine, they create a ferrous oxide, which can also be known as a ferric oxide. This is what a variable valency is.

Other elements that have variable valency are transitional metals. Examples of these include Cd(OH)2], FeCl3, and HgI2. They can have one or more valency.

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Victoria Martian

Victoria Martian

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Victoria Martian
Victoria Martian, Blogger, B.com in Journalism, New York

Answered Jan 19, 2021

Transition metals, such as nickel, copper, iron, and tin exhibit variable valency. Valency is the combining ability of an element. The number of electrons provided or accepted by an atom of an element to have the nearest noble gas's electronic configuration is called valency.

Electrons can participate in the creation of chemical bonds. Some elements meet with other atoms to give, accept, barter, or trade electrons in varying amounts depending on the reaction's essence. These are known as valence elements. Iron combines with oxygen to create ferrous oxide as well as ferric oxide.

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F. Hope

F. Hope

F. Hope
F. Hope

Answered Jan 19, 2021

There are different metals that are available that will be able to exhibit variable valency. Some of these metals are tin, copper, lead, iron, lead. The metals will donate electrons from their valence shell. By doing this, they will be able to create positively charged ions.

The main reason why some metals will be able to show valency easily is due to the involvement of the d−orbitals. This will make the different electrons that can be found in the outermost shells to become involved in the whole reaction. The electronic configurations of the metals will make a lot of difference for sure.

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O. Bickis

O. Bickis

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O. Bickis
O. Bickis, Corporate employee, MBA, Stockton

Answered Jan 14, 2021

Metals like iron are examples of transition metals, which is why they exhibit variable valency. All transition metals show this behavior. This happens when the d-orbitals also lose their valence electrons when forming bonds with other elements or ligands.

Naturally, transition elements use the electrons in their s-orbitals when forming bonds, but they can still use electrons in their incomplete d-orbitals to form bonds with other elements. For instance, iron can lose the two electrons in its valence shell when forming bonds, and it can still use the electrons in its penultimate shell to form bonds.

That is why iron can have oxidation numbers of +2 and +3. This can be attributed to the energy difference between their orbitals. Another reason why some elements show variable valency is because of the difference in their electronic configurations. This is why, in a particular group, you might notice a progressive decrease in the oxidation number.

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W. Mocroft

W. Mocroft

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W. Mocroft
W. Mocroft, Philanthropist, Master Degree in International Business, Las Vegas

Answered Nov 23, 2018

Iron, like tin, copper and nickel is a transitional metal and these have a variable valency. To be clear, valency is how many hydrogen atoms can combine or displace one of the atoms to form a compound. The combination or sharing of electrons in different proportions depends on the nature of the reaction.

For example, iron combines with oxygen to form ferrous oxide as well as ferric oxide. This is termed variable valency. In the case of transitional metals, these have variable valency because some elements can have more than one valency.

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F. Lopez

F. Lopez

F. Lopez
F. Lopez

Answered May 29, 2018

To understand variable valency it helps to first understand what is meant by an atom’s valency. Outside an atom’s nucleus are orbiting electrons, looking to accept or donate one or more of its electrons in order to achieve a more stable state. Transition metals, such as nickel, copper, tin, and iron exhibit variable valency.

Looking at iron as an example, when iron loses three electrons to form an ionic bond with oxygen, the compound formed is called ferric oxide. Iron can also lose two electrons to form an ionic bond with oxygen to form ferrous oxide. Calling iron compounds by the words ferric and ferrous are derived from the Latin name for iron, which is ferrum.

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